diff --git a/phpunit/src/CompilerBaseApiTest.php b/phpunit/src/CompilerBaseApiTest.php
index 1af04faa..34f4bbbe 100644
--- a/phpunit/src/CompilerBaseApiTest.php
+++ b/phpunit/src/CompilerBaseApiTest.php
@@ -1415,6 +1415,56 @@ YAML);
         $this->assertSame(['prime2'], $consumer->getLinkLibs());
     }
 
+    public function testLibraryBuildRejectsExportedNativeClass(): void
+    {
+        global $translator;
+        $translator = $this->compiler;
+        $this->setPropertyValue('buildMode', CompilerBase::BUILD_MODE_LIB);
+
+        $file = $this->fixturePath('library_exported_native.php');
+        $this->compiler->addFiles([$file]);
+
+        $this->expectException(TestError::class);
+        $this->expectExceptionMessage(
+            'Native class `LibraryExportedNative` cannot be exported through a library stub; mark it with #[NoExport]',
+        );
+        $this->compiler->prepareFile($file);
+    }
+
+    public function testNoExportNativeClassIsOmittedFromLibraryStub(): void
+    {
+        global $translator;
+        $translator = $this->compiler;
+        $this->setPropertyValue('buildMode', CompilerBase::BUILD_MODE_LIB);
+        $this->setPropertyValue('outputDir', $this->testDir);
+        $this->compiler->setTargetName('hidden_native');
+
+        $file = $this->fixturePath('library_hidden_native.php');
+        $this->compiler->addFiles([$file]);
+        $this->compiler->prepareFile($file);
+        $this->compiler->convertFile($file);
+
+        $stub = file_get_contents($this->compiler->genLibraryImportStub([$file]));
+        $this->assertStringContainsString('function library_visible_value(): int', $stub);
+        $this->assertStringNotContainsString('LibraryHiddenNative', $stub);
+        $this->assertStringNotContainsString('#[Native]', $stub);
+    }
+
+    public function testLibraryStubGeneratorRejectsExportedNativeClassWithoutPrepare(): void
+    {
+        $this->setPropertyValue('buildMode', CompilerBase::BUILD_MODE_LIB);
+        $this->setPropertyValue('outputDir', $this->testDir);
+        $this->compiler->setTargetName('exported_native');
+
+        $this->expectException(\TypePhp\Exception\SyntaxError::class);
+        $this->expectExceptionMessage(
+            'Native class `LibraryExportedNative` cannot be exported through a library stub; mark it with #[NoExport]',
+        );
+        $this->compiler->genLibraryImportStub([
+            $this->fixturePath('library_exported_native.php'),
+        ]);
+    }
+
     public function testNoExportFollowsPhpNamespaceResolution(): void
     {
         $this->setPropertyValue('buildMode', CompilerBase::BUILD_MODE_LIB);
diff --git a/phpunit/src/HotPathCodegenTest.php b/phpunit/src/HotPathCodegenTest.php
index 97e13f3a..80217461 100644
--- a/phpunit/src/HotPathCodegenTest.php
+++ b/phpunit/src/HotPathCodegenTest.php
@@ -9,7 +9,7 @@ final class HotPathCodegenTest extends \BaseTest
         $code = $this->compileFixture();
 
         self::assertStringContainsString('items.item(0L, true) = value;', $code);
-        self::assertStringContainsString('items.append(value);', $code);
+        self::assertStringContainsString('items.appendValue(value);', $code);
         self::assertStringContainsString('items.item(0L, true) += value;', $code);
         self::assertStringContainsString('items.item(0L, true) += other.get(0L);', $code);
         self::assertStringContainsString('items.item(2L, true) = other.get(0L);', $code);
diff --git a/phpunit/src/NativeClass/NativeClassValidationTest.php b/phpunit/src/NativeClass/NativeClassValidationTest.php
index c7f7a730..8d225f6e 100644
--- a/phpunit/src/NativeClass/NativeClassValidationTest.php
+++ b/phpunit/src/NativeClass/NativeClassValidationTest.php
@@ -98,6 +98,15 @@ final class NativeClassValidationTest extends \BaseTest
         $this->compile('native-class-anonymous.php');
     }
 
+    public function testRejectsNativeClassDeclaredInStubFile(): void
+    {
+        $this->expectException(TestError::class);
+        $this->expectExceptionMessage(
+            '#[Native] cannot be used in .stub.php; Native class layout must be owned by the TypePHP compiler',
+        );
+        $this->compile('native-class-stub.stub.php');
+    }
+
     public function testRejectsUntypedProperty(): void
     {
         $this->expectException(TestError::class);
diff --git a/src/Generator/LibraryImportStubGenerator.php b/src/Generator/LibraryImportStubGenerator.php
index 2b793b16..5ae11a15 100644
--- a/src/Generator/LibraryImportStubGenerator.php
+++ b/src/Generator/LibraryImportStubGenerator.php
@@ -14,6 +14,7 @@ use PhpParser\NodeTraverser;
 use PhpParser\NodeVisitor\NameResolver;
 use PhpParser\Parser;
 use PhpParser\PrettyPrinter;
+use TypePhp\Exception\SyntaxError;
 use TypePhp\Transform\CompileTimeAttribute;
 use TypePhp\Transform\CompileTimeAttributeRegistry;
 
@@ -103,6 +104,14 @@ final class LibraryImportStubGenerator
         if ($this->hasNoExportAttribute($stmt)) {
             return null;
         }
+        if ($stmt instanceof Node\Stmt\Class_ && $this->hasNativeAttribute($stmt)) {
+            $name = isset($stmt->namespacedName)
+                ? $stmt->namespacedName->toString()
+                : ($stmt->name?->toString() ?? '<anonymous>');
+            throw new SyntaxError(
+                "Native class `{$name}` cannot be exported through a library stub; mark it with #[NoExport]",
+            );
+        }
 
         $comments = array_filter(
             $stmt->getComments(),
@@ -163,6 +172,18 @@ final class LibraryImportStubGenerator
         return null;
     }
 
+    private function hasNativeAttribute(Node\Stmt\Class_ $class): bool
+    {
+        foreach ($class->attrGroups as $group) {
+            foreach ($group->attrs as $attribute) {
+                if (CompileTimeAttribute::is($attribute, 'Native')) {
+                    return true;
+                }
+            }
+        }
+        return false;
+    }
+
     private function hasNoExportAttribute(Node $node): bool
     {
         if (!property_exists($node, 'attrGroups')) {
diff --git a/src/Preprocessor.php b/src/Preprocessor.php
index 516a900b..8bab8059 100644
--- a/src/Preprocessor.php
+++ b/src/Preprocessor.php
@@ -954,6 +954,24 @@ class Preprocessor extends CompilerBase
         $this->classDef = new ClassDef($this->class, $flags, $this->namespace);
         $this->classDef->nativeObject = NativeClassAttributeLowering::isNative($class);
         $this->classDef->exported = !$this->hasNoExportAttribute($class);
+        if ($this->classDef->nativeObject && $this->stubFile) {
+            $this->fatalCompileTimeAttribute(
+                $class,
+                'Native',
+                '#[Native] cannot be used in .stub.php; Native class layout must be owned by the TypePHP compiler',
+            );
+        }
+        if ($this->classDef->nativeObject
+            && $this->classDef->exported
+            && $this->isBuildModeLib()
+            && !$this->isWasiTarget()
+        ) {
+            $this->fatalCompileTimeAttribute(
+                $class,
+                'Native',
+                "Native class `{$fullClassName}` cannot be exported through a library stub; mark it with #[NoExport]",
+            );
+        }
         $this->classDef->methodsForTarget = $this->parseMethodsForTarget($class);
         $this->addClass($fullClassName, $this->classDef);